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Studies synthesis of polymeric materials, emphasizing interrelationships of chemical pathways, process conditions, and microarchitecture of molecules produced.
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Description
Chemical pathways include traditional approaches such as anionic polymerization, radical condensation, and ring-opening polymerizations. Other techniques are discussed, including stable free radical polymerizations and atom transfer free radical polymerizations (ARTP), catalytic approaches to well-defined architectures, and polymer functionalization in bulk and at surfaces. Process conditions include bulk, solution, emulsion, suspension, gas phase, and batch vs. continuous fluidized bed. Microarchitecture includes tacticity, molecular-weight distribution, sequence distributions in copolymers, errors in chains such as branches, head-to-head addition, and peroxide incorporation.
Acknowledgements
The instructor would like to thank Karen Shu and Karen Daniel for their work in preparing material for this course site.
Course content
- Course Overview Unlimited
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- Molecular Weight (MW) Control Unlimited
- Step Growth Polymerization Unlimited
- Common Processing Approaches Unlimited
- Interfacial Polymerizations Unlimited
- Other Polymers of Interest Obtained by Step-Growth Unlimited
- Crosslinking and Branching Unlimited
- Network Formation Unlimited
- Step-by-Step Approaches I: Polypeptide Synthesis: Examples from Biology Unlimited
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- Introduction to Radical Polymerization Unlimited
- Radical Polymerization Unlimited
- Free Radical Kinetic Chain Length Unlimited
- Thermodynamics of Free Radical Polymerizations Unlimited
- Processing Approaches: Emulsion Polymerization Processes Unlimited
- Processing Approaches: Suspension (Bead) Polymerization Processes Unlimited
- Ziegler-Natta Catalysis Unlimited
- Stereoregular Polymerizations Unlimited
- Radical Copolymerization: Alternating to Block Copolymers Unlimited
- Metallocene Chemistry Unlimited
- Introduction to Anionic Polymerization Unlimited
- Living Anionic Polymerization Unlimited
- Anionic Block Copolymerization Unlimited
- Anionic Ring Opening Polymerization Unlimited
- Introduction to Cationic Polymerization Unlimited
- “Living” Cationic Polymerizations Unlimited
- Anionic Ring Opening Polymerization Unlimited
- Polysiloxanes, Lactams, etc. Unlimited
- Surface Functionalization of Polymers, Graft Copolymerization Unlimited
- “Living” Free Radical Approaches: Stable Free Radical Polymerization Unlimited
- ATRP Unlimited
- ROMP Unlimited
- Inorganic Polymer Synthesis Unlimited
- Macromolecular Systems Via Secondary Bonding: Use of H-bonding and Ionic Charge to Build Structures Unlimited
Instructor
