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This course introduces principles and mathematical models of electrochemical energy conversion and storage.
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What you'll learn
Course content
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Description
Students study equivalent circuits, thermodynamics, reaction kinetics, transport phenomena, electrostatics, porous media, and phase transformations. In addition, this course includes applications to batteries, fuel cells, supercapacitors, and electrokinetics.
Course content
Introduction
Basic Physics of Galvanic Cells, Electrochemical Energy Conversion
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2011 Lecture 1: Basic Physics of Galvanic Cells
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2011 Lecture 2: Electrochemical Energy Conversion
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Electrochemical Energy Storage
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2011 Lecture 3: Electrochemical Energy Storage
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Circuit Models
2011 Lecture 4: Dynamics of Equivalent Circuits
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2011 Lecture 5: Impedance spectroscopy
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2011 Lecture 6: Impedance of Electrode
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Thermodynamics
2011 Lecture 7: Statistical Thermodynamics
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2011 Lecture 8: The Nernst Equation
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2011 Lecture 9: Fuel Cells and Lead-Acid Batteries
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Pourbaix Diagram
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2011 Lecture 9: Fuel Cells and Lead-Acid Batteries
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Metal Acid Batteries, Lemon Battery Demo
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Li-ion Batteries, Pseudocapacitance
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2011 Lecture 10: Li-ion Batteries
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2011 Lecture 37: Pseudocapacitors and Batterie
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Ideal Solution Model, Linear Sweep Voltammetry
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2011 Lecture 11: Reconstitution Electrodes
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2011 Lecture 11: Reconstitution Electrodes
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Kinetics
2011 Lecture 14: Faradaic Reactions in Concentrated Solutions
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2011 Lecture 12: Faradaic Reactions in Dilute Solutions
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2011 Lecture 13: Butler-Volmer Equation
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Electrocatalysis
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2011 Lecture 15: Ion Adsorption and Intercalation
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Electrochemical Phase Transformations
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Homogeneous Charge Transfer
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Heterogeneous Charge Transfer
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Charge Transfer at Metal Electrodes
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Transport Phenomena
2011 Lecture 16: Concentration Polarization
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2011 Lecture 19: Transient Diffusion
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2011 Lecture 20: Warburg Impedance
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Forced Convection I
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2011 Lecture 17: Forced Convection in Fuel Cells (I)
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Forced Convection II
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2011 Lecture 18: Forced Convection in Fuel Cells II
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2011 Lecture 21: Solids and Concentrated Solutions
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2011 Lecture 22: Transport in Bulk Electrolytes
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Homogeneous Reaction-diffusion
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2011 Lecture 22: Transport in Bulk Electrolytes
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2011 Lecture 23: Ion Concentration Polarization
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2011 Lecture 24: Diffuse Charge in Electrolyte
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2011 Lecture 25: Diffuse Double Layer Structure
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2011 Lecture 32: Percolation
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2011 Lecture 33: Macroscopic Conductivity of Composite
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2011 Lecture 34: Transport in Porous Media
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2012 Lecture 36–37: Scaling Analysis of Energy Storage
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2011 Lecture 35: Porous Electrodes (I. Supercapacitors)
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2011 Lecture 36: Electrochemical Supercapacitor
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2011 Lecture 37: Pseudocapacitors and Batteries
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Instructor
Massachusetts Institute of Technology
5
5
1
1925
1520
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