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Introduction to Organometallic Chemistry. Instructor: Prof. A. G. Samuelson, Department of Inorganic and Physical Chemistry, IISc Bangalore. This course deals with structure, bonding and reactivity of organometallic compounds: compounds that feature a metal carbon bond.
1111 years
40
Teaching organometallic chemistry is a daunting task for the instructor. A number of new concepts have to be introduced in the very first lecture. This happens because simple bonding models that help one understand organic compounds and metal complexes do not explain the structures and reactivity of many organometallic compounds and several new bonding models developed and refined in the last fifty years have to be suddenly thrust on the hapless student. Meanwhile, synthesis of new organometallic compounds continue unabated and have led to the study and discovery of fascinating reactions. Many of these reactions and compounds, having no similarity to what the student has been exposed to in organic chemistry giving the student no option but to memorize. (from nptel.ac.in)
Course Currilcum
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- Lecture 01 – Introduction to Organometallic Chemistry Unlimited
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- Lecture 02 – Metal Carbonyl Complexes Unlimited
- Lecture 03 – Metal Carbonyls Unlimited
- Lecture 04 – Ligand Substitution Reactions Unlimited
- Lecture 05 – Substitutes for Carbonyl Ligands Unlimited
- Lecture 06 – Carbene Complexes Unlimited
- Lecture 07 – Carbene Complexes (cont.) Unlimited
- Lecture 08 – Non-Carbon Ancillary Ligands Unlimited
- Lecture 09 – Non-Carbon Ancillary Ligands (cont.) Unlimited
- Lecture 10 – Metal Alkyl Complexes Unlimited
- Lecture 11 – Ligand Insertion Reactions Unlimited
- Lecture 12 – Metal Alkene Complexes Unlimited
- Lecture 13 – Alkynes η2 Bonding Unlimited
- Lecture 14 – Metal Dihydrogen and Hydrides Unlimited
- Lecture 15 – Migratory Insertion Reaction with Alkynes Unlimited
- Lecture 16 – ηm (m=4 Dienes and m=2n, Polyenes) Unlimited
- Lecture 22 – Metal-alkyls – η3 Complex-synthesis, Bonding Unlimited
- Lecture 23 – Metal-alkyls – η3 Complex-fluxionality, Reactivity Unlimited
- Lecture 24 – C-C Single Bond Forming Reactions Unlimited
- Lecture 29 – The Isolable Analogy Unlimited
- Lecture 30 – Fluxional Properties of Organometallics Unlimited
- Lecture 31 – Quantifying Steric and Electronic Factors Unlimited
- Lecture 38 – Asymmetric Catalysis Unlimited
- Lecture 39 – Medicinal Applications of Organometallic Complexes Unlimited
- Lecture 40 – Special Properties and Applications Unlimited
