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September 23, 2023

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Description

Chemistry 202: Organic Reaction Mechanisms II (Winter 2014, UC Irvine). Instructor: Professor David Van Vranken.

Topics include the shape of frontier molecular orbitals, nucleophilic sigma bonds, the organic chemistry of phosphorus and sulfur, pericyclic reactions, ene reactions, electrocyclic reactions, sigmatropic reactions, kinetics, rate equations, selectivity and reaction coordinate-energy diagrams, transition state theory, and radical reactions.

Course Curriculum

  • Lecture 01 – Introduction Unlimited
  • Lecture 02 – A Review of Orbitals Unlimited
  • Lecture 03 – The Shape of Frontier Molecular Orbitals Unlimited
  • Lecture 04 – Nucleophilic Sigma Bonds Unlimited
  • Lecture 05 – Nucleophilic Sigma Bonds (cont.) Unlimited
  • Lecture 06 – The Organic Chemistry of Phosphorus Unlimited
  • Lecture 07 – Phosphorus Chemistry (cont.), The Organic Chemistry of Sulfur Unlimited
  • Lecture 08 – The Organic Chemistry of Sulfur (cont.), Pericyclic Reactions Unlimited
  • Lecture 09 – Pericyclic Reactions: The Diels-Alder Reaction Unlimited
  • Lecture 10 – Pericyclic Reactions: The Diels-Alder Reaction (cont.) Unlimited
  • Lecture 11 – Beyond [4+2] Cycloadditions Unlimited
  • Lecture 12 – Retrocycloadditions, Ene Reactions Unlimited
  • Lecture 13 – Electrocyclic Reactions Unlimited
  • Lecture 14 – Electrocyclic Reactions (cont.), Sigmatropic Reactions Unlimited
  • Lecture 15 – Sigmatropic Reactions (cont.) Unlimited
  • Lecture 16 – Kinetics and Rate Equations Unlimited
  • Lecture 17 – Rate Equations (cont.), Selectivity and Reaction Coordinate-Energy Diagrams Unlimited
  • Lecture 18 – Selectivity and Reaction Coordinate-Energy Diagrams Unlimited
  • Lecture 19 – Selectivity (cont.), Transition State Theory Unlimited
  • Lecture 20 – Transition State Theory, Temperature, and Half-Lives Unlimited
  • Lecture 21 – Mechanistic Tools Unlimited
  • Lecture 22 – Radical Structure and Reactivity Unlimited
  • Lecture 23 – Radical Reactions Unlimited

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